卢萍萍;吴鸿飞;王书渠;童静芝;黄国波;

• 1:台州学院医药化工学院
• 2:仙居县科技情报研究中心

摘要(Abstract)：

简述了单螺环磷酸酯、双螺环磷酸酯、笼状磷酸酯等几种单组分膨胀型阻燃剂的合成及应用研究进展,结果认为,单组分膨胀型阻燃剂是集酸源、炭源、气源于同一分子内的阻燃剂,是无卤阻燃剂的主要发展方向之一。

关键词(KeyWords)： 膨胀型阻燃剂;单组分;磷酸酯;述评

Abstract:

Keywords:

基金项目(Foundation): 国家级大学生创新创业训练计划项目(项目编号:201310350012)资助

作者(Authors): 卢萍萍;吴鸿飞;王书渠;童静芝;黄国波;

参考文献(References)：

• [1]李巧玲,欧育湘.一种含P-N键的双环磷酸酯化合物的合成及晶体结构[J].结构化学,2001,20(2):128-130.
• [2]张丽萍.1,3,2-二氧磷杂环己烷衍生物的合成和阻燃性能的研究[D].武汉:华中师范大学,2004.
• [3]Yong T Y,Wang D Y,Jing X K,et al.A formaldehyde-free flame retardant wood particleboard system based on two-component polyurethane adhesive[J].J Appl Polym Sci,2008,108:1216-1222.
• [4]刘畅.新型磷氮系阻燃剂的合成-结构及阻燃性能研究[D].武汉:华中师范大学,2006.
• [5]Huang G B,Wang X,Fei Z D,et al.Poly(methyl methacrylate)/montmorillonite nanocomposites prepared with a novel reactive phosphorus–nitrogen-containing monomer of N-[2-(5,5-dimethyl-1,3,2-dioxaphosphinyl-2-ylamino)ethyl]-acrylamide and its thermal and flame retardant properties[J].J Appl Polym Sci,2012,124:5037-5045.
• [6]Huang G B,Liang H D,Wang X,et al.Poly(acrylic acid)/clay thin films assembled by layer-by-layer deposition for improving the flame retardancy properties of cotton[J].Ind Eng Chem Res,2012,51:12299-12309.
• [7]黄国波,高建荣,贾建洪,等.磷氮型季铵盐及其制备方法和应用[P].CN200910101560.5,2009.
• [8]黄国波,高建荣,贾建洪,等.有机磷氮系-蒙脱土/LDPE纳米复合材料的制备及阻燃性能研究[J].复合材料学报,2010,27:45-52.
• [9]Huang G B,Guo H C,Wang X,et al.Effect of phosphorus-nitrogen containing quaternary ammonium salts structure on the flammability properties of poly(methyl methacrylate)/montmorillonitenanocomposites[J].Ind Eng Chem Res,2013,52:4089-4097.
• [10]赵文革,马志领,刘志广.螺环磷酸酯酰胺阻燃剂的合成及其在醇酸清漆中的应用[J].河北大学学报(自然科学版),1996,16(2):20-23.
• [11]Huang G B,Zhu B C,Shi H B.Combination effect of organics-modified montmorillonite with intumescent flame retardants on thermal stability and fire behavior of polyethylene nanocomposites[J].J Appl Polym Sci,2011,121:1285-1291.
• [12]Ma H Y,Tong L F,Xu Z B,et al.A novel intumescent flame retardant:synthesis and application in ABS copolymer[J].Polym Degrad Stab,2007,92:720-726.
• [13]Ma H Y,Tong L F,Xu Z B,et al.Functionalizing carbon nanotubes by grafting on intumescent flame retardant:nanocomposite synthesis,morphology,rheology,and flammability[J].Adv Funct Mater,2008,18:414-421.
• [14]Huang G B,Tang S W,Gao J R.A novel intumescent flame retardant-functionalized graphene:Nanocomposite synthesis,characterization,and flammability properties[J].Mater Chem Phys,2012,135:938-947.
• [15]李昕,欧育湘,张蕴宏.三(1-氧代-1-磷杂-2,6,7-三氧杂双环[2.2.2]辛烷-4-亚甲基)磷酸酯的合成、晶体结构及热性能[J].高等化学学报,2002,23(4):695-699.
• [16]徐旭荣,陈关喜,胡耿源.磷杂螺环化合物的合成及表征[J].精细化工,1997,14(5):35-38.
• [17]吴志平,舒万艮,熊联明,等.笼状磷酸酯三聚氰铵盐阻燃剂的合成及阻燃性能研究[J].化工技术与开发,2003,32(6):1-3.
• [18]Gao F,Tong L F,Fang Z P.Effect of a novel phosphorouse nitrogen containing intumescentflame retardant on the fire retardancy and the thermal behaviourof poly(butylene terephthalate)[J].Polym Degrad Stab,2006,91:1295-1299.
• [19]Song P A,Liu H,Shen Y,et al.Fabrication of dendrimer-like fullerene(C60)-decorated oligomeric intumescent flame retardant for reducing the thermal oxidation and flammability of polypropylene nanocomposites[J].J Mater Chem,2009,19:1305-1313.
• [20]Kannan P,Gangadhara,Kishore K.Synthesis and spectral studies of polyami de-phosphate ester from phosphine-oxide-containing diols with aryl phosphorod ichloridates and their thermal and flammability behavior[J].Polymer,1991,32:1909-1913.
• [21]陆正鸣,程博闻,黄翔宇,等.一种阻燃剂及其制备方法和使用该阻燃剂的阻燃腈纶:中国,CN101113211[P],2008.
• [22]Tang Y,Hu Y,Li B G,et al.Polypropylene/montmorillonite nanocomposites and intumescent,flame-retardant montmorillonite synergism in polypropylene nanocomposites[J].J Polym Sci Polym Chem,2004,42:6163-6173.