加工工艺对MCOPA／HDPE阻隔性能影响Effect of Process Conditions on Barrier Properties of Modified Copolyamide/HDPE
王国成;罗会鹏;李海峰;蒋涛;
摘要(Abstract)：
由乙烯-丙烯酸酯-马来酸酐共聚物(CP)与共聚尼龙(COPA)在双螺杆挤出机中进行反应共混制备改性共聚尼龙(MCOPA)。采用MCOPA／高密度聚乙烯(HDPE)材料制备高阻隔性中空吹塑瓶。对制品的加工工艺、阻隔性能、形态结构等进行了研究。结果表明,加工工艺对制品阻隔性能会有很大的影响。同时形态分析表明．吹塑瓶瓶口、瓶身、瓶底各个部位的横断面和纵断面都具有清晰、连续的层状结构。
关键词(KeyWords)： 共聚尼龙;高密度聚乙烯;层状结构;阻隔性能;吹塑
基金项目(Foundation): 该课题为国家“863”计划基金项目(项目号2002AA333080)。
作者(Authors): 王国成;罗会鹏;李海峰;蒋涛;
参考文献(References)：
- 1 Subramanian P M. Permeability barriers by controlled morphology of polymer blends. Polymer Engineering & Science, 1985, 25(8): 483-487
- 2 Chien Cheng, Fan Chiang, Jen Taut Yeh,et al. Effects of composition of modified polyamide on barrier properties of polyethylene/modified polyamide blends. Journal of Applied Polymer Science, 1997, 64(8): 1 531-1 540
- 3 Subramanian P M, Mehra V. Laminar morphology in polymer blends: structure and properties. Polymer Engineering & Science, 1987, 27(9): 663-668
- 4 Yeh J T, Fan Chiang,Cho C C,et al. Effects of compatibilizer precursors on the barrier properties and morphology of polyethylene/polyamide blends. Polymer Bulletin, 1995, 35 (3): 371-378
- 5 Valenza A, Visco A M, Acierno D. Characterization of blends with polyamide 6 and ethylene acrylic acid copolymers at different acrylic acid content. Polymer Testing, 2002, 21: 101-109
- 6 Koulouri E G, Georgaki A X,Kallitsis J K. Reactive compatiblization of aliphatic polyamides with functionalized polyeth ylenes. Polymer,1997, 38(16):4 185-4 192
- 7 Chau Fae Jyan, Jen Taut Yeh, Shun Syu Yang, et al. Influence of compatiblization and viscosity ratio on the barrier and impact properties of blends of a modified polyamide-6 and polyethylene. Polymer Engineering & Science, 1999, 39(10): 1 952-1 961